| NL - Pitching - SP - ESPN Player Rating | ||||||||||||||
| RK | PLAYER | TEAM | IP | W | L | SV | BS | K | BB | HBP | BAA | HR | ERA | RAT |
| 1 | Gio Gonzalez | WSH | 54.0 | 6 | 1 | 0 | 0 | 69 | 22 | 1 | .167 | 1 | 1.98 | 59.4 |
| 2 | Cole Hamels | PHI | 62.0 | 7 | 1 | 0 | 0 | 66 | 13 | 2 | .220 | 5 | 2.17 | 54.0 |
| 3 | Brandon Beachy | ATL | 61.0 | 5 | 2 | 0 | 0 | 44 | 15 | 0 | .183 | 4 | 1.77 | 50.3 |
| 4 | Clayton Kershaw | LAD | 68.0 | 4 | 2 | 0 | 0 | 57 | 15 | 0 | .194 | 6 | 1.97 | 46.2 |
| 5 | Chris Capuano | LAD | 56.0 | 6 | 1 | 0 | 0 | 50 | 19 | 1 | .201 | 5 | 2.25 | 43.8 |
| 6 | Wade Miley | ARI | 52.0 | 6 | 1 | 0 | 0 | 32 | 16 | 2 | .241 | 2 | 2.41 | 40.5 |
| 7 | Wandy Rodriguez | HOU | 67.0 | 4 | 4 | 0 | 0 | 45 | 15 | 2 | .234 | 4 | 2.14 | 39.9 |
| 8 | Lance Lynn | STL | 56.0 | 7 | 1 | 0 | 0 | 52 | 19 | 3 | .213 | 4 | 2.54 | 38.7 |
| 9 | Stephen Strasburg | WSH | 58.0 | 5 | 1 | 0 | 0 | 70 | 17 | 3 | .223 | 4 | 2.64 | 37.5 |
| 10 | Johnny Cueto | CIN | 64.0 | 5 | 2 | 0 | 0 | 41 | 14 | 5 | .270 | 5 | 2.53 | 36.8 |
| 11 | James McDonald | PIT | 57.0 | 3 | 2 | 0 | 0 | 58 | 18 | 1 | .198 | 2 | 2.51 | 36.5 |
| 12 | Kyle Lohse | STL | 62.0 | 5 | 1 | 0 | 0 | 36 | 9 | 3 | .261 | 4 | 2.90 | 34.1 |
| 13 | Ryan Dempster | CHC | 54.0 | 0 | 3 | 0 | 0 | 50 | 15 | 0 | .213 | 3 | 2.14 | 33.9 |
| 14 | Matt Cain | SF | 71.0 | 4 | 2 | 0 | 0 | 66 | 13 | 3 | .209 | 6 | 2.92 | 28.5 |
| 15 | Jordan Zimmermann | WSH | 58.0 | 3 | 4 | 0 | 0 | 40 | 11 | 2 | .234 | 5 | 2.47 | 24.8 |
| 16 | Johan Santana | NYM | 59.0 | 2 | 2 | 0 | 0 | 60 | 16 | 0 | .225 | 4 | 2.75 | 24.7 |
| 17 | Carlos Zambrano | MIA | 60.0 | 2 | 3 | 0 | 0 | 44 | 25 | 3 | .207 | 4 | 2.85 | 22.0 |
| 18 | Zack Greinke | MIL | 59.0 | 5 | 2 | 0 | 0 | 62 | 15 | 0 | .269 | 2 | 3.66 | 20.8 |
| 19 | Bud Norris | HOU | 62.0 | 5 | 1 | 0 | 0 | 62 | 22 | 3 | .246 | 6 | 3.34 | 20.7 |
| 20 | Ryan Vogelsong | SF | 54.0 | 3 | 2 | 0 | 0 | 38 | 23 | 1 | .222 | 4 | 2.50 | 20.7 |
| 21 | Anibal Sanchez | MIA | 59.0 | 2 | 3 | 0 | 0 | 62 | 16 | 2 | .229 | 4 | 2.87 | 20.1 |
| 22 | Madison Bumgarner | SF | 66.0 | 5 | 4 | 0 | 0 | 47 | 14 | 1 | .235 | 7 | 3.14 | 20.1 |
| 23 | Ted Lilly | LAD | 48.0 | 5 | 1 | 0 | 0 | 31 | 19 | 2 | .203 | 3 | 3.14 | 19.2 |
| 24 | Mark Buehrle | MIA | 69.0 | 5 | 4 | 0 | 0 | 34 | 11 | 2 | .254 | 7 | 3.26 | 18.1 |
| 25 | Tommy Hanson | ATL | 57.0 | 5 | 3 | 0 | 0 | 51 | 23 | 2 | .251 | 5 | 3.12 | 14.0 |
| 26 | R.A. Dickey | NYM | 64.0 | 6 | 1 | 0 | 0 | 60 | 16 | 1 | .231 | 8 | 3.08 | 13.5 |
| 27 | Jeff Samardzija | CHC | 57.0 | 4 | 3 | 0 | 0 | 57 | 18 | 2 | .234 | 4 | 3.00 | 13.4 |
| 28 | Cliff Lee | PHI | 51.0 | 0 | 2 | 0 | 0 | 47 | 8 | 0 | .225 | 6 | 2.82 | 12.0 |
| 29 | Jaime Garcia | STL | 64.0 | 3 | 3 | 0 | 0 | 49 | 17 | 0 | .297 | 1 | 3.78 | 12.0 |
| 30 | Roy Halladay | PHI | 72.0 | 4 | 4 | 0 | 0 | 56 | 14 | 2 | .252 | 6 | 3.98 | 11.8 |
| 31 | Ricky Nolasco | MIA | 61.0 | 5 | 2 | 0 | 0 | 34 | 16 | 3 | .270 | 6 | 4.26 | 8.0 |
| 32 | Bronson Arroyo | CIN | 58.0 | 2 | 2 | 0 | 0 | 44 | 8 | 1 | .284 | 8 | 3.22 | 6.5 |
| 33 | Tim Hudson | ATL | 39.0 | 3 | 2 | 0 | 0 | 24 | 11 | 3 | .257 | 1 | 4.12 | 6.3 |
| 34 | Clayton Richard | SD | 64.0 | 2 | 6 | 0 | 0 | 39 | 20 | 1 | .255 | 9 | 4.76 | 4.5 |
| 35 | Vance Worley | PHI | 44.0 | 3 | 2 | 0 | 0 | 45 | 15 | 1 | .268 | 7 | 3.07 | 4.2 |
| 36 | Jake Westbrook | STL | 56.0 | 4 | 3 | 0 | 0 | 38 | 16 | 2 | .271 | 3 | 3.38 | 4.2 |
| 37 | Ian Kennedy | ARI | 62.0 | 3 | 5 | 0 | 0 | 52 | 16 | 4 | .284 | 9 | 4.65 | 3.5 |
| 38 | Edwin Jackson | WSH | 58.0 | 1 | 2 | 0 | 0 | 50 | 12 | 1 | .221 | 6 | 3.38 | 3.2 |
| 39 | Matt Garza | CHC | 53.0 | 2 | 2 | 0 | 0 | 49 | 18 | 2 | .220 | 7 | 3.91 | 2.7 |
| 40 | Tim Lincecum | SF | 53.0 | 2 | 5 | 0 | 0 | 58 | 29 | 1 | .271 | 4 | 6.41 | 2.3 |
| 41 | Josh Johnson | MIA | 57.0 | 2 | 3 | 0 | 0 | 45 | 18 | 1 | .313 | 3 | 4.87 | 2.1 |
| 42 | Edinson Volquez | SD | 65.0 | 2 | 4 | 0 | 0 | 55 | 34 | 1 | .228 | 3 | 3.46 | 2.0 |
| 43 | Lucas Harrell | HOU | 58.0 | 4 | 3 | 0 | 0 | 28 | 24 | 1 | .253 | 3 | 3.72 | 1.5 |
| 44 | Dillon Gee | NYM | 56.0 | 4 | 3 | 0 | 0 | 52 | 16 | 3 | .277 | 7 | 4.92 | 1.2 |
| 45 | Paul Maholm | CHC | 50.0 | 4 | 3 | 0 | 0 | 29 | 17 | 6 | .245 | 9 | 4.62 | 1.2 |
| 46 | J.A. Happ | HOU | 51.0 | 4 | 3 | 0 | 0 | 48 | 20 | 0 | .276 | 9 | 4.56 | 1.2 |
| 47 | Anthony Bass | SD | 58.0 | 2 | 5 | 0 | 0 | 55 | 21 | 0 | .236 | 6 | 3.55 | 0.8 |
| 48 | Mike Minor | ATL | 58.0 | 2 | 4 | 0 | 0 | 51 | 21 | 2 | .288 | 13 | 6.98 | 0.3 |
| 49 | Yovani Gallardo | MIL | 58.0 | 3 | 4 | 0 | 0 | 53 | 28 | 0 | .249 | 6 | 4.19 | 0.3 |
