Last season's Hall of Fame game was canceled because of the NFL lockout.
New Orleans will be playing in the game for the fifth time, most recently in a 20-7 loss to the Pittsburgh Steelers in 2007. Arizona will be back for the fourth time, and first since 1986.
The game comes a day after six players, including Saints tackle Willie Roaf, are inducted into the Hall of Fame.
NFL Network will televise the game, which starts at 8 p.m. ET, the league announced Wednesday.